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Degredation Mechanisms Side Group Elimination

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GC, Pyrolysis
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Degredation Mechanisms Depolymerization
|CDS Analytical|Technical notes
#15a Degredation Mechanisms Depolymerization Application Note Pyrolysis Theory When heated, polymers generally undergo thermal de­gradation in one of three basic mechanisms - depolymerization, side group elimination, or ran­dom scission. Depolymerization is a free radical mechanism in which the polymer essentially…
Key words
methacrylate, methacrylatemonomer, monomerdepo­, depo­polyethyl, polyethylreverts, revertsdegredation, degredationdepolymerization, depolymerizationethyl, ethylradical, radicalpyroprobe, pyroprobemonomers, monomerschromatogram, chromatogramdegrade, degradetheory, theoryunsaturated
Degredation Mechanisms - Random Scission
|CDS Analytical|Technical notes
Degredation Mechanisms - Random Scission Application Note Theory During pyrolysis, polymeric materials may degrade via a number of mechanisms which are generally grouped into three classes - random scission, depo­lymerization, and side group elimination. Random scission results from the production…
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olig­omers, olig­omersdegredation, degredationmacromolecule, macromoleculescission, scissionradicals, radicalsrepeating, repeatingpyroprobe, pyroprobebackbone, backbonerandom, randomtheory, theorydiffering, differingreveal, revealmechanisms, mechanismscauses, causesfrequently
FIELD APPLICATION REPORT GAS CHROMATOGRAPH Y Polymer Degradation Mechanisms u s i n g P y r o l y s i s- G C / M S Author: Thomas Wampler CDS Analytical, Inc. 465 Limestone Road Oxford , PA…
Key words
poly, polypyrolysis, pyrolysisunzipping, unzippingwampler, wamplerscission, scissionmacromolecule, macromoleculedelay, delayinterscan, interscanthomas, thomasrandom, randomoven, oventransfer, transfermultiplier, multiplierperkinelmer, perkinelmerline
FIELD APPLICATION REPORT GAS CHROMATOGRAPH Y Polymer Degradation Mechanisms u s i n g P y r o l y s i s- G C / M S Author: Thomas Wampler CDS Analytical, Inc. 465 Limestone Road Oxford , PA…
Key words
poly, polypyrolysis, pyrolysisunzipping, unzippingwampler, wamplermacromolecule, macromoleculescission, scissiondelay, delayinterscan, interscanthomas, thomasrandom, randomoven, oventransfer, transferperkinelmer, perkinelmermultiplier, multiplierline
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